Hitler would have used them. There is no doubt in my mind about that. The problem would have been a delivery method. We have discussed this before and the Luftwaffe had no plane capable of carrying an atomic bomb of the 1940's.
Let's just skip to the targets though. I started to think it would depend upon the time frame they became available. I changed my mind. He would use the weapon on the Russians. The Russians were primarily a slavic people which the Nazi doctrine considered sub-human. The Russian people, either in a concentrated city area or in a troop concentration would receive the attack. After the news got around about the devastation then he would have used that power to blackmail and bully what he wanted out of everyone else.
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PEOPLE SLEEP PEACEABLY IN THEIR BEDS AT NIGHT ONLY BECAUSE ROUGH MEN STAND READY TO DO VIOLENCE ON THEIR BEHALF. GEORGE ORWELL
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